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263 results

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Page 1
Carbonyl and ester C-O bond hydrosilylation using kappa(4)-diimine nickel catalysts.
Rock CL , Groy TL , Trovitch RJ . Rock CL , et al. Dalton Trans. 2018 Jul 3;47(26):8807-8816. doi: 10.1039/c8dt01857j. Dalton Trans. 2018. PMID: 29922802
However, when an equimolar solution of allyl acetate and phenyl silane was added to 1.0 mol% (Ph2PPrDI)Ni, complete ester C-O bond hydrosilylation was observed within 30 min at 25 C to generate propylene and PhSi(OAc)3. ...This activity is believed to be the highest …
However, when an equimolar solution of allyl acetate and phenyl silane was added to 1.0 mol% (Ph2PPrDI)Ni, complete ester C-O …
Determination of plasma and leukocyte vitamin C concentrations in a randomized, double-blind, placebo-controlled trial with Ester-C().
Mitmesser SH, Ye Q, Evans M, Combs M. Mitmesser SH, et al. Springerplus. 2016 Jul 25;5(1):1161. doi: 10.1186/s40064-016-2605-7. eCollection 2016. Springerplus. 2016. PMID: 27512620 Free PMC article.
The objective of this study was to evaluate the bioavailability of vitamin C in plasma (reflective of recent intake) and leukocytes (reflective of tissue stores and influences on immune function) from a novel vitamin C formulation, Ester-C(). METHODS: The study was …
The objective of this study was to evaluate the bioavailability of vitamin C in plasma (reflective of recent intake) and leukocytes (reflect …
Safety and tolerance of ester-C compared with regular ascorbic acid.
Gruenwald J, Graubaum HJ, Busch R, Bentley C. Gruenwald J, et al. Adv Ther. 2006 Jan-Feb;23(1):171-8. doi: 10.1007/BF02850358. Adv Ther. 2006. PMID: 16644619 Clinical Trial.
The goal of this randomized, double-blind crossover clinical trial in 50 healthy volunteers sensitive to acidic foods was to evaluate whether Ester-C calcium ascorbate causes fewer epigastric adverse effects than are produced by regular ascorbic acid ( …
The goal of this randomized, double-blind crossover clinical trial in 50 healthy volunteers sensitive to acidic foods was to evaluate whethe …
(Adamantan-1-yl)(phenyl-sulfan-yl)methanone.
El-Azab AS, Abdel-Aziz AA, Al-Swaidan IA, Ng SW, Tiekink ER. El-Azab AS, et al. Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):o2104. doi: 10.1107/S1600536812026116. Epub 2012 Jun 16. Acta Crystallogr Sect E Struct Rep Online. 2012. PMID: 22798782 Free PMC article.
Two independent mol-ecules (A and B) comprises the asymmetric unit of the title ester, C(17)H(20)OS. The phenyl ring is inclined with respect to the thio-carboxyl group, forming dihedral angles of 58.95 (6) (in mol-ecule A) and 62.28 (6) (in mol-ecule B). ...
Two independent mol-ecules (A and B) comprises the asymmetric unit of the title ester, C(17)H(20)OS. The phenyl ring is inclin …
2,4,6-Tri-nitro-phenyl 3-bromo-benzoate.
Moreno-Fuquen R, Mosquera F, Ellena J, Tenorio JC. Moreno-Fuquen R, et al. Acta Crystallogr Sect E Struct Rep Online. 2014 May 21;70(Pt 6):o689. doi: 10.1107/S1600536814010952. eCollection 2014 Jun 1. Acta Crystallogr Sect E Struct Rep Online. 2014. PMID: 24940266 Free PMC article.
In the title picryl-substituted ester, C13H6BrN3O8, the mean plane of the central ester C-O-C(=O)-C fragment (r.m.s. deviation= 0.0186 A) is rotated by 84.73 (7) and 19.92 (12) to the picryl and phenyl rings, respectively. ...
In the title picryl-substituted ester, C13H6BrN3O8, the mean plane of the central ester C-O-C(=O)-C fragment (r.m.s. deviation …
Iron-Catalyzed C(sp2)-C(sp3) Cross-Coupling of Aryl Chlorobenzoates with Alkyl Grignard Reagents.
Bisz E, Szostak M. Bisz E, et al. Molecules. 2020 Jan 6;25(1):230. doi: 10.3390/molecules25010230. Molecules. 2020. PMID: 31935934 Free PMC article.
It is notable that high selectivity for the cross-coupling is achieved in the presence of hydrolytically-labile and prone to nucleophilic addition phenolic ester C(acyl)-O bonds. The reaction provides access to alkyl-functionalized aryl benzoates. The examination of …
It is notable that high selectivity for the cross-coupling is achieved in the presence of hydrolytically-labile and prone to nucleophilic ad …
Thermodynamic Strategies for C-O Bond Formation and Cleavage via Tandem Catalysis.
Lohr TL, Li Z, Marks TJ. Lohr TL, et al. Acc Chem Res. 2016 May 17;49(5):824-34. doi: 10.1021/acs.accounts.6b00069. Epub 2016 Apr 14. Acc Chem Res. 2016. PMID: 27078085
This Account reviews recent developments on thermodynamically leveraged tandem catalysis for ether and more recently, ester C-O bond cleavage undertaken at Northwestern University. First, the fundamentals of lanthanide-catalyzed hydroelementation are reviewed, with …
This Account reviews recent developments on thermodynamically leveraged tandem catalysis for ether and more recently, ester C- …
Herbicidal properties of antihypertensive drugs: calcium channel blockers.
Abdullah HSTSH, Chia PW, Omar D, Chuah TS. Abdullah HSTSH, et al. Sci Rep. 2021 Jul 9;11(1):14227. doi: 10.1038/s41598-021-93662-2. Sci Rep. 2021. PMID: 34244589 Free PMC article.
At concentrations of 125 to 250 mg/L, the 5-(3-Fluoro-phenyl)-7-methyl-5H-thiazolo[3,2-a]pyrimidine-6-carboxylic acid ethyl ester (c) was highly active against Oldenlandia verticillata and Eleusine indica. At application rates of 1.25 to 2.5 kg ai/ha, formulated c d …
At concentrations of 125 to 250 mg/L, the 5-(3-Fluoro-phenyl)-7-methyl-5H-thiazolo[3,2-a]pyrimidine-6-carboxylic acid ethyl ester ( …
Cyclodecyl 4-nitrophenylacetate.
Brown J, Pawar DM, Fronczek FR, Noe EA. Brown J, et al. Acta Crystallogr C. 2006 Oct;62(Pt 10):o628-30. doi: 10.1107/S0108270106035049. Epub 2006 Sep 21. Acta Crystallogr C. 2006. PMID: 17008754
An intermolecular contact exists between the ester C atom and a nitro O atom, having a C...O distance of 2.909 (2) A....
An intermolecular contact exists between the ester C atom and a nitro O atom, having a C...O distance of 2.909 (2) A....
263 results