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Graphdiyne-Based Single-Atom Catalysts with Different Coordination Environments.
Fu X, Zhao X, Lu TB, Yuan M, Wang M. Fu X, et al. Angew Chem Int Ed Engl. 2023 Apr 11;62(16):e202219242. doi: 10.1002/anie.202219242. Epub 2023 Feb 13. Angew Chem Int Ed Engl. 2023. PMID: 36723492 Review.
The coordination environment of single atoms anchored on GDY plays a key role in their catalytic performance. The mini-review highlights state-of-the-art progress in the rational design of GDY-based ACs and their applications, and mainly reveals the relationship between th …
The coordination environment of single atoms anchored on GDY plays a key role in their catalytic performance. The mini-review highlig …
Access to Alkenyl Cyclobutanols by Ni-Catalyzed Regio- and Enantio-Selective syn-Hydrometalative 4-exo-trig Cyclization of Alkynones.
Li XL, Deng JL, Long J, Fu YF, Zheng YQ, Liu WB. Li XL, et al. Angew Chem Int Ed Engl. 2024 Oct 11:e202415164. doi: 10.1002/anie.202415164. Online ahead of print. Angew Chem Int Ed Engl. 2024. PMID: 39394042
Experimental and computational mechanistic studies indicate that the reaction is initiated by an active Ni-H species, with carbonyl-directed hydrometalation as the key for regioselective control. This catalytic method provides a general solution for regioselective hydrofun …
Experimental and computational mechanistic studies indicate that the reaction is initiated by an active Ni-H species, with carbonyl-directed …