Disassembly Mechanisms and Energetics of Polymetallic Rings and Rotaxanes.
Geue N, Bennett TS, Arama AA, Ramakers LAI, Whitehead GFS, Timco GA, Armentrout PB, McInnes EJL, Burton NA, Winpenny REP, Barran PE.
Geue N, et al.
J Am Chem Soc. 2022 Dec 14;144(49):22528-22539. doi: 10.1021/jacs.2c07522. Epub 2022 Dec 2.
J Am Chem Soc. 2022.
PMID: 36459680
Free PMC article.
Here, we apply ion mobility mass spectrometry coupled with density functional theory to investigate the disassembly mechanisms and energetics of a family of heterometallic rings and rotaxanes with the general formula [NH(2)RR'][Cr(7)MF(8)(O(2)C(t)Bu)(16)] with M = Mn(II), Fe(II), …
Here, we apply ion mobility mass spectrometry coupled with density functional theory to investigate the disassembly mechanisms and energetic …