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Microbial rhodoquinone biosynthesis proceeds via an atypical RquA-catalyzed amino transfer from S-adenosyl-L-methionine to ubiquinone.
Neupane T, Chambers LR, Godfrey AJ, Monlux MM, Jacobs EJ, Whitworth S, Spawn JE, Clingman SHK, Vergunst KL, Niven FM, Townley JJ, Orion IW, Goodspeed CR, Cooper KA, Cronk JD, Shepherd JN, Langelaan DN. Neupane T, et al. Among authors: chambers lr. Commun Chem. 2022 Aug 1;5(1):89. doi: 10.1038/s42004-022-00711-6. Commun Chem. 2022. PMID: 36697674 Free PMC article.