Cusumano AQ - Search Results

1

Mechanism of Ni-Catalyzed Photochemical Halogen Atom-Mediated C(sp³)-H Arylation.

Cusumano AQ, Chaffin BC, Doyle AG. Cusumano AQ, et al. J Am Chem Soc. 2024 Jun 5;146(22):15331-15344. doi: 10.1021/jacs.4c03099. Epub 2024 May 22. J Am Chem Soc. 2024. PMID: 38778454 Free PMC article.

2

Reaction Mechanism, Origins of Enantioselectivity, and Reactivity Trends in Asymmetric Allylic Alkylation: A Comprehensive Quantum Mechanics Investigation of a C(sp³)-C(sp³) Cross-Coupling.

Cusumano AQ, Stoltz BM, Goddard WA 3rd. Cusumano AQ, et al. J Am Chem Soc. 2020 Aug 12;142(32):13917-13933. doi: 10.1021/jacs.0c06243. Epub 2020 Jul 30. J Am Chem Soc. 2020. PMID: 32640162 Free PMC article.

3

Divergent Catalysis: Catalytic Asymmetric [4+2] Cycloaddition of Palladium Enolates.

Flesch KN, Cusumano AQ, Chen PJ, Strong CS, Sardini SR, Du YE, Bartberger MD, Goddard WA 3rd, Stoltz BM. Flesch KN, et al. Among authors: cusumano aq. J Am Chem Soc. 2023 May 24;145(20):11301-11310. doi: 10.1021/jacs.3c02104. Epub 2023 May 15. J Am Chem Soc. 2023. PMID: 37186945 Free PMC article.

4

The Transition Metal Catalyzed [π2s + π2s + σ2s + σ2s] Pericyclic Reaction: Woodward-Hoffmann Rules, Aromaticity, and Electron Flow.

Cusumano AQ, Goddard WA 3rd, Stoltz BM. Cusumano AQ, et al. J Am Chem Soc. 2020 Nov 11;142(45):19033-19039. doi: 10.1021/jacs.0c09575. Epub 2020 Oct 27. J Am Chem Soc. 2020. PMID: 33107727 Free PMC article.

5

Global Diastereoconvergence in the Ireland-Claisen Rearrangement of Isomeric Enolates: Synthesis of Tetrasubstituted α-Amino Acids.

Fulton TJ, Cusumano AQ, Alexy EJ, Du YE, Zhang H, Houk KN, Stoltz BM. Fulton TJ, et al. Among authors: cusumano aq. J Am Chem Soc. 2020 Dec 30;142(52):21938-21947. doi: 10.1021/jacs.0c11480. Epub 2020 Dec 15. J Am Chem Soc. 2020. PMID: 33320668 Free PMC article.

6

Ir-Catalyzed Asymmetric Allylic Alkylation of Dialkyl Malonates Enabling the Construction of Enantioenriched All-Carbon Quaternary Centers.

Moghadam FA, Hicks EF, Sercel ZP, Cusumano AQ, Bartberger MD, Stoltz BM. Moghadam FA, et al. Among authors: cusumano aq. J Am Chem Soc. 2022 May 11;144(18):7983-7987. doi: 10.1021/jacs.2c02960. Epub 2022 Apr 27. J Am Chem Soc. 2022. PMID: 35476460 Free PMC article.

7

Molecular Dynamics Investigations of Dienolate [4 + 2] Reactions.

Chen PJ, Cusumano AQ, Flesch KN, Strong CS, Goddard WA 3rd, Stoltz BM. Chen PJ, et al. Among authors: cusumano aq. J Am Chem Soc. 2024 May 8;146(18):12758-12765. doi: 10.1021/jacs.4c02681. Epub 2024 Apr 29. J Am Chem Soc. 2024. PMID: 38682865 Free PMC article.

8

Identifying the Imperative Role of Metal-Olefin Interactions in Catalytic C-O Reductive Elimination from Nickel(II).

Lohrey TD, Cusumano AQ, Goddard WA 3rd, Stoltz BM. Lohrey TD, et al. Among authors: cusumano aq. ACS Catal. 2021 Aug 20;11(16):10208-10222. doi: 10.1021/acscatal.1c02790. Epub 2021 Aug 2. ACS Catal. 2021. PMID: 35186424 Free PMC article.

9

Multireference Description of Nickel-Aryl Homolytic Bond Dissociation Processes in Photoredox Catalysis.

Cagan DA, Stroscio GD, Cusumano AQ, Hadt RG. Cagan DA, et al. Among authors: cusumano aq. J Phys Chem A. 2020 Dec 3;124(48):9915-9922. doi: 10.1021/acs.jpca.0c08646. Epub 2020 Nov 23. J Phys Chem A. 2020. PMID: 33226235

10

Correction to "Reaction Mechanism, Origins of Enantioselectivity, and Reactivity Trends in Asymmetric Allylic Alkylation: A Comprehensive Quantum Mechanics Investigation of a C(sp³)-C(sp³) Cross-Coupling".

Cusumano AQ, Stoltz BM, Goddard WA 3rd. Cusumano AQ, et al. J Am Chem Soc. 2020 Dec 16;142(50):21233. doi: 10.1021/jacs.0c11706. Epub 2020 Dec 4. J Am Chem Soc. 2020. PMID: 33274922 No abstract available.

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