Calcium influx factor, further evidence it is 5, 6-epoxyeicosatrienoic acid

J Biol Chem. 1999 Jan 1;274(1):175-82. doi: 10.1074/jbc.274.1.175.

Abstract

We present evidence in astrocytes that 5,6-epoxyeicosatrienoic acid, a cytochrome P450 epoxygenase metabolite of arachidonic acid, may be a component of calcium influx factor, the elusive link between release of Ca2+ from intracellular stores and capacitative Ca2+ influx. Capacitative influx of extracellular Ca2+ was inhibited by blockade of the two critical steps in epoxyeicosatrienoic acid synthesis: release of arachidonic acid from phospholipid stores by cytosolic phospholipase A2 and cytochrome P450 metabolism of arachidonic acid. AAOCF3, which inhibits cytosolic phospholipase A2, blocked thapsigargin-stimulated release of arachidonic acid as well as thapsigargin-stimulated elevation of intracellular free calcium. Inhibition of P450 arachidonic acid metabolism with SKF525A, econazole, or N-methylsulfonyl-6-(2-propargyloxyphenyl)hexanamide, a substrate inhibitor of P450 arachidonic acid metabolism, also blocked thapsigargin-stimulated Ca2+ influx. Nano- to picomolar 5, 6-epoxyeicosatrienoic acid induced [Ca2+]i elevation consistent with capacitative Ca2+ influx. We have previously shown that 5, 6-epoxyeicosatrienoic acid is synthesized and released by astrocytes. When 5,6-epoxyeicosatrienoic acid was applied to the rat brain surface, it induced vasodilation, suggesting that calcium influx factor may also serve a paracrine function. In summary, our results suggest that 5,6-epoxyeicosatrienoic acid may be a component of calcium influx factor and may participate in regulation of cerebral vascular tone.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, P.H.S.

MeSH terms

  • 8,11,14-Eicosatrienoic Acid / analogs & derivatives*
  • 8,11,14-Eicosatrienoic Acid / antagonists & inhibitors
  • 8,11,14-Eicosatrienoic Acid / metabolism
  • 8,11,14-Eicosatrienoic Acid / pharmacology
  • Animals
  • Arachidonic Acid / pharmacology
  • Astrocytes / drug effects
  • Astrocytes / metabolism
  • Calcium / metabolism*
  • Cytochrome P-450 Enzyme Inhibitors
  • Enzyme Inhibitors / pharmacology
  • Ion Transport
  • Phospholipases A / antagonists & inhibitors
  • Phospholipases A2
  • Rats
  • Signal Transduction
  • Thapsigargin / antagonists & inhibitors
  • Thapsigargin / pharmacology

Substances

  • Cytochrome P-450 Enzyme Inhibitors
  • Enzyme Inhibitors
  • Arachidonic Acid
  • Thapsigargin
  • 5,6-epoxy-8,11,14-eicosatrienoic acid
  • 14,15-epoxy-5,8,11-eicosatrienoic acid
  • Phospholipases A
  • Phospholipases A2
  • 8,11,14-Eicosatrienoic Acid
  • Calcium