Control of hepatic fatty acid oxidation by 5'-AMP-activated protein kinase involves a malonyl-CoA-dependent and a malonyl-CoA-independent mechanism

Arch Biochem Biophys. 1997 Jan 15;337(2):169-75. doi: 10.1006/abbi.1996.9784.

Abstract

Incubation of rat hepatocytes with 5-aminoimidazole-4-carboxamide ribonucleoside (AICAR), an activator of the 5'-AMP-activated protein kinase (AMPK), produced a twofold stimulation of palmitate oxidation and of the activity of carnitine palmitoyltransferase I (CPT-I), together with a profound decrease of the activity of acetyl-CoA carboxylase and of the intracellular level of malonyl-CoA. AICAR-induced CPT-I stimulation progressively blunted with time after cell permeabilization, pointing to reversal of conformational constraints of the enzyme in control cells due to the permeabilization-triggered dilution of intracellular malonyl-CoA. The stimulation stabilized at a steady 20-25%. This 20-25% increase in CPT-I activity survived upon complete removal of malonyl-CoA from the permeabilized cells, indicating that it was not dependent on the malonyl-CoA concentration of the cell. This malonyl-CoA-independent activation of CPT-I was not evident when mitochondria were isolated for assay of enzyme activity or when cells were disrupted by vigorous sonication. In addition, the microtubule stabilizer taxol prevented the malonyl-CoA-independent stimulation of CPT-I induced by AICAR. Hence, stimulation of hepatic fatty acid oxidation by AMPK seems to rely on the activation of CPT-I by two different mechanisms: deinhibition of CPT-I induced by depletion of intracellular malonyl-CoA levels and malonyl-CoA-independent stimulation of CPT-I, which might involve modulation of interactions between CPT-I and cytoskeletal components.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • AMP-Activated Protein Kinases
  • Acetyl-CoA Carboxylase / metabolism
  • Aminoimidazole Carboxamide / analogs & derivatives
  • Aminoimidazole Carboxamide / metabolism
  • Aminoimidazole Carboxamide / pharmacology
  • Animals
  • Caprylates / metabolism
  • Carnitine O-Palmitoyltransferase / metabolism*
  • Enzyme Activation
  • Fatty Acids / metabolism*
  • In Vitro Techniques
  • Liver / cytology
  • Liver / metabolism*
  • Male
  • Malonyl Coenzyme A / metabolism*
  • Microtubules / drug effects
  • Microtubules / physiology
  • Mitochondria, Liver / enzymology
  • Multienzyme Complexes / metabolism*
  • Okadaic Acid / pharmacology
  • Oxidation-Reduction
  • Paclitaxel / pharmacology
  • Palmitates / metabolism
  • Protein Kinases / metabolism*
  • Protein Serine-Threonine Kinases*
  • Rats
  • Rats, Wistar
  • Ribonucleotides / metabolism
  • Ribonucleotides / pharmacology

Substances

  • Caprylates
  • Fatty Acids
  • Multienzyme Complexes
  • Palmitates
  • Ribonucleotides
  • Okadaic Acid
  • Aminoimidazole Carboxamide
  • Malonyl Coenzyme A
  • Carnitine O-Palmitoyltransferase
  • Protein Kinases
  • Protein Serine-Threonine Kinases
  • AMP-Activated Protein Kinases
  • Acetyl-CoA Carboxylase
  • AICA ribonucleotide
  • Paclitaxel