Atomically Precise Cu Nanoclusters: Recent Advances, Challenges, and Perspectives in Synthesis and Catalytic Applications

Abstract

Atomically precise metal nanoclusters are an emerging type of nanomaterial which has diverse interfacial metal-ligand coordination motifs that can significantly affect their physicochemical properties and functionalities. Among that, Cu nanoclusters have been gaining continuous increasing research attentions, thanks to the low cost, diversified structures, and superior catalytic performance for various reactions. In this review, we first summarize the recent progress regarding the synthetic methods of atomically precise Cu nanoclusters and the coordination modes between Cu and several typical ligands and then discuss the catalytic applications of these Cu nanoclusters with some explicit examples to explain the atomical-level structure-performance relationship. Finally, the current challenges and future research perspectives with some critical thoughts are elaborated. We hope this review can not only provide a whole picture of the current advances regarding the synthesis and catalytic applications of atomically precise Cu nanoclusters, but also points out some future research visions in this rapidly booming field.

Keywords: Atomically precise Cu nanoclusters; Catalytic applications; Challenges and perspectives; Controllable synthesis; Structure–performance relationship.