Correlation Between the Magnetic Properties of Ce-Containing Magnets and the CeFe2 Phase at Various Sintering Temperatures

Materials (Basel). 2024 Nov 12;17(22):5517. doi: 10.3390/ma17225517.

Abstract

This article investigates the relationship between the magnetic properties of magnets and the percentage and distribution of the CeFe2 phase at different sintering temperatures. At the lower sintering temperature, the grain boundary phase flow of the magnet is poor, more hole defects are generated in the magnet, and the comprehensive magnetic properties of the magnet are poor. An increase in sintering temperature increases the ratio of CeFe2 phase, improves the fluidity of grain boundary liquid phase, fills the hole defects and causes an increase in remanence. However, an increase in grain size also inhibits the coercivity of the magnet at this temperature. When the sintering temperature reaches 1080 °C, the CeFe2 phase ratio continues to increase, providing more liquid phase. The phase Ce2Fe17 was also decomposed into liquid phase, the continuity and wettability of grain boundary phase were optimized, and the coercivity reached a maximum of 13.18 kOe. However, the orientation of the magnet changed and the proportion of the main phase decreased, resulting in a slight decrease in the remanence (Br = 13.17 kGs).

Keywords: Ce2Fe17 phase; CeFe2 phase; liquid phase sintering; magnetic property.