Rapid surface acetylation of cellulosic materials at room temperature by immersion method

Abstract

Regulating the surface hydrophobicity of cellulosic materials via surface acetylation can greatly extend their applications. However, most of the existing surface acetylation methods for cellulosic materials are time-consuming and costly. Herein a simple but practical immersion method for the rapid surface acetylation of cellulose materials was reported, which involved soaking cellulosic materials in alkaline aqueous solution followed by immersed them in vinyl acetate. Results showed that simply wetting the surface of cellulosic materials with aqueous alkaline solutions can satisfy their surface acetylation requirement, and the consumption of esterifying agent can be significantly reduced. The immersion method can rapidly improve the surface properties of the cellulosic materials at room temperature within minutes and which is highly attractive to the surface acetylation of cellulose fibers. The moisture regain of the viscose filament obviously decreased after surface acetylation. When the surface acetylated viscose fiber was used as cigarette filter, the total particulate matter in the filtered cigarette smoke significantly reduced from 11.03 mg/cigarette to 6.03 mg/cigarette. The products are promising alternatives to the existing cigarette filters.

Keywords: Acetylation; Cellulose; Cigarette filter; Transesterification; Viscose fiber.