For the first time, simple and facile fabrication of a magnetic alginate microadsorbent via piezoelectric inkjet technology was developed for the selective removal of 137Cs via magnetic separation. Through the ejection of an alginate solution containing potassium ferrocyanide and magnetic nanoparticles (MNPs) into a Cu2+ solution via an inkjet device, the fabrication of a copper ferrocyanide-embedded magnetic alginate microadsorbent (CuFC-MAM) with an average size of 39.38 μm was easily achieved in a one-pot fabrication process; here, the Cu2+ ions acted as both a cross-linker for the gelation of alginate and a Cu source for the in situ synthesis of CuFC with potassium ferrocyanide. The Cs adsorption behavior of CuFC-MAM was effectively fitted by the pseudo-second-order kinetic model and Langmuir isotherm. Owing to the increased specific surface area of CuFC-MAM, its pseudo-second-order rate constant and maximum adsorption capacity were 76.54 and 1.486 times greater than those of CuFC-embedded magnetic alginate macroadsorbents fabricated without inkjet devices. Compared with other Cs adsorbents, CuFC-MAM presented the highest maximum capacity and Kd value; these results were attributed to the high content of CuFC in CuFC-MAM (50.15%). In addition, our CuFC-MAM exhibited an excellent removal efficiency of radioactive Cs, exceeding 99% from seawater.
Keywords: Alginate microgel; Copper ferrocyanide; Cs adsorption; Inkjet; Magnetic adsorbent.
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