Single-Atom Barium Promoter Enormously Enhanced Non-Noble Metal Catalyst for Ammonia Decomposition

Angew Chem Int Ed Engl. 2024 Nov 5:e202416195. doi: 10.1002/anie.202416195. Online ahead of print.

Abstract

As a well-established topic, single-atom catalyst has drawn growing interest for its high utilization of metal. However, researchers prefer to develop various active metals with single-atom form, the intrinsic roles of single-atom promoters are usually underrated, which are significant in boosting reaction activity. In this work, Ba single atoms were in situ prepared in the Co-Ba/Y2O3 catalyst with crystallized BaCO3 as the precursor under the ammonia decomposition reaction condition. The optimized Co-Ba/Y2O3 catalyst achieves extremely high H2 production rate of 138.3 mmolH2 ⋅ gcat -1 ⋅ min-1 at very low temperature (500 °C, GHSV=840,000 mL ⋅ g-1 ⋅ h-1) and Co-Ba/Y2O3 exhibits excellent durability during the 350 h test, which realizes the highest activity among all non-noble catalysts, and reaches or even exceeds numerous reported Ru-based catalysts. Both Y2O3 and Co demonstrate positive interactions with Ba, which significantly facilitates the dispersion of Ba species at high temperatures (≥600 °C). Ba single atoms significantly enhance the charge density of Co and form additionally active Co-O-Ba-Y2O3 interfacial sites, which alleviates hydrogen poisoning and decreases the reaction barrier of the N-H bond activation of *NH. The exploration of atomically dispersed promoters is groundbreaking in heterogeneous catalysis, which opens up a whole new domain of catalytic material.

Keywords: Ammonia decomposition reaction; Hydrogen poisoning; Non-noble metal catalyst; Single-atom Ba promoter; Yttrium oxide.