Surface modification of surgical suture by chitosan-based biocompatible hybrid coatings: In-vitro anti-corrosion, antibacterial, and in-vivo wound healing studies

Int J Biol Macromol. 2024 Nov;281(Pt 4):136571. doi: 10.1016/j.ijbiomac.2024.136571. Epub 2024 Oct 15.

Abstract

This work aims to develop chitosan-based biocompatible hybrid coatings on synthetic surgical sutured by direct current electrophoretic deposition (DC-EPD) method. The chitosan (CS), curcumin (CR), aloe-vera (AV), and 2-aminothiazolidin-4-one-5-ethanoic acid (AT) were used as suspensions of varying combinations and compositions (A-I). Each suspension has a further 05 samples (Aa-Ae-Ia-Ie) at selected DC-EPD set parameters (2-10 V, t; 240 s, D; 1 cm). Potentiodynamic polarization measurements (PDP) were carried out in the ringer solution. Among all samples, Ed (CS, 1.6 g/L; 8 V) and Hb (CS-CR-AT, 1.6 g/Leach; 4 V) have shown greatest corrosion inhibition efficiency (IEPDP: 99 %), least corrosion rates (CR; 0.001 mm/y and 0.017 mm/y, respectively), and least corrosion current density (Icorr.; 0.01 A cm-2). SEM and FTIR further confirmed these two best coatings stable and corrosion resistant before and after performing corrosion test, while the coating thickness by profilometry test was found to be greater (16.28 μm) for Hb. Mechanical stress and strain of bare and coated samples were found to have no significant difference. Antibacterial activity revealed greater resistance of Hb against S. aureus as compared to Ed. In-vivo incision wound model study further revealed better healing and less inflammation with coated sutures with comparatively enhanced wound healing effect of Hb coated suture.

Keywords: Anti-corrosion potential; Antibacterial & wound healing effect; DC-EPD hybrid coatings on surgical suture.

MeSH terms

  • Animals
  • Anti-Bacterial Agents* / chemistry
  • Anti-Bacterial Agents* / pharmacology
  • Chitosan* / chemistry
  • Chitosan* / pharmacology
  • Coated Materials, Biocompatible* / chemistry
  • Coated Materials, Biocompatible* / pharmacology
  • Corrosion
  • Male
  • Materials Testing
  • Microbial Sensitivity Tests
  • Rats
  • Staphylococcus aureus / drug effects
  • Surface Properties
  • Sutures*
  • Wound Healing* / drug effects

Substances

  • Chitosan
  • Anti-Bacterial Agents
  • Coated Materials, Biocompatible