Unveiling the untapped potential of Hibiscus Rosa-sinensis lignocellulosic fiber: A multifaceted characterization for advancing sustainable biocomposite applications

Abstract

In the pursuit of sustainable advancements in bio-inspired fiber reinforced polymer composite materials, the exploration of novel natural fibers has become a focal point of research. This experimental study aims to elucidate the unexplored potential of Hibiscus Rosa-sinensis fiber (HRF) as a versatile reinforcement material for high-performance composites. Through an integrated approach, this research offers a meticulous analysis of the HRF's physico-chemical properties, and single fiber tensile strength. The crystalline structure are revealed by X-ray diffraction (XRD), thermal behavior are characterized through thermo-gravimetric analysis (TGA), and surface morphology has been visualized using field emission scanning electron microscopy (FESEM) studies. From the results, it is found that the HRF contains a cellulose content of 79.50 %, positioning it as a prime bast fiber among its counterparts. This composition is complemented by hemicellulose (10.36 %), lignin (4.62 %), wax (0.84 %), and ash (2.96 %). The Fourier-transform infrared spectroscopy (FTIR) spectra unveils the intricate functional groups present in the fibers. XRD analysis highlights a crystallinity index (CI) of 66.93 %, confirming a well-organized and structured crystalline arrangement. The thermal stability established through TGA underscores HRF's resilience up to 284 °C, presenting it is an optimal reinforcement material for bio-inspired green composites operating within 280 °C. The surface morphology of HRF is examined through FESEM and three-dimensional profiling, showcasing its inherent morphological intricacies. The multidimensional characterization provided herein contributes significantly to the evolving landscape of biocomposite research, fostering a platform for future advancements and innovations in HRF-based composite materials.

Keywords: Biocomposite applications; Hibiscus Rosa-sinensis; Lignocellulosic fiber; Physico-chemical properties; Single fiber tensile strength; Sustainability.