A unique diversity in chemical properties of lanthanide compounds making them very useful in various important applications stems not least from the existence of less common Ln oxidation states, in particular +2. However, the molecular properties of low-valency lanthanide compounds are not yet well studied even for the most stable divalent Ln-containing species, such as europium dihalides. In this paper, highly accurate molecular structures, vibrational spectra, and atomisation energies of the europium dihalides EuX2 (X = F, Cl, Br, I) are obtained at the complete basis set CCSD(T) level. All of the EuX2 species are calculated to be non-linear (C2v) exhibiting a regular increase in X-Eu-X bond angle on passing through the halogen series (F → Cl → Br → I), from 117° in EuF2 to 141° in EuI2, which is accompanied by a rapid decrease in the barriers to linearity, h = E(D∞h) - E(C2v), from 2180 cm-1 to 166 cm-1, respectively. The Eu-X bonds in EuX2 appear to be longer but energetically stronger than those in the respective monohalides EuX, whose properties are studied in this work at the same level of theory as EuX2. The performance of the Ln 4f-in-core pseudopotential (PP) approximation for EuX2 is assessed by comparing the Eu PP-based coupled-cluster (CC) calculations with all-electron CC benchmarks. Incorporating the Eu 4f electrons into the PP is shown to cause large errors: up to 10 deg. in X-Eu-X bond angles, 80% in barriers to linearity, and 0.05 Å in the Eu-X bond lengths, which proves the necessity of an explicit treatment of 4f electrons if high accuracy is the goal. The present results set a benchmark in the field of low-valency lanthanide chemistry, in particular for the calibration of DFT functionals.