Protective effect of ferulic acid-hyaluronic acid copolymer against UVB irradiation in a human HaCaT cell line

Int J Biol Macromol. 2024 Nov;279(Pt 4):135570. doi: 10.1016/j.ijbiomac.2024.135570. Epub 2024 Sep 11.

Abstract

Excessive UVB exposure increased the production of reactive oxygen species (ROS), leading to oxidative damage and epidermal inflammation. To enhance UVB protection effect, a strong phenolic antioxidant, ferulic acid (FA) was designed onto HA via a free radical mediated method. Our previous work has confirmed its structural characterization and in vitro antioxidant. The aim of this study was to evaluate its protective effects against UVB-induced damage in human HaCaT cells. We observed a significant reduction in cell viability to 57.43 % following UVB exposure at a dose of 80 mJ/cm2. However, pretreatment with FA-HA (250 to 2000 μg·mL-1) significantly attenuated cytotoxicity in a dose-dependent manner. Furthermore, FA-HA was found to suppress the intracellular generation of ROS and up-regulated the expression of the antioxidant enzyme superoxide dismutase (SOD). The elevated levels of pro-inflammatory cytokines, including interleukin-1 beta (IL-1β), interleukin-6 (IL-6), interleukin-8 (IL-8) and tumor necrosis factor-alpha (TNF-α) as well as the mRNA expression of matrix metalloproteinase-1/9 (MMP-1/9) induced by UVB irradiation, were also effectively reduced by FA-HA. Additionally, FA-HA treatment decreases the phosphorylation of mitogen-activated protein kinase (MAPK) and activator protein-1 (AP-1), ultimately preventing apoptosis. These findings suggest that FA-HA is a promising candidate for UVB protection in skincare formulations.

Keywords: FA-HA; HaCaT cells; UVB protection.

MeSH terms

  • Antioxidants / chemistry
  • Antioxidants / pharmacology
  • Cell Survival* / drug effects
  • Coumaric Acids* / chemistry
  • Coumaric Acids* / pharmacology
  • Cytokines / metabolism
  • HaCaT Cells*
  • Humans
  • Hyaluronic Acid* / chemistry
  • Hyaluronic Acid* / pharmacology
  • Oxidative Stress / drug effects
  • Oxidative Stress / radiation effects
  • Polymers / chemistry
  • Polymers / pharmacology
  • Radiation-Protective Agents / chemistry
  • Radiation-Protective Agents / pharmacology
  • Reactive Oxygen Species* / metabolism
  • Superoxide Dismutase / metabolism
  • Ultraviolet Rays* / adverse effects

Substances

  • Coumaric Acids
  • ferulic acid
  • Hyaluronic Acid
  • Reactive Oxygen Species
  • Cytokines
  • Antioxidants
  • Radiation-Protective Agents
  • Superoxide Dismutase
  • Polymers