Ionizable nanoemulsions for RNA delivery into the central nervous system - importance of diffusivity

J Control Release. 2024 Aug:372:295-303. doi: 10.1016/j.jconrel.2024.06.051. Epub 2024 Jun 24.

Abstract

Lipid nanoparticles (LNPs) currently dominate the RNA delivery landscape; however their limited diffusivity hampers targeted tissue dissemination, and, hence, their capacity for intracellular drug delivery. This is especially relevant for tissues such as the central nervous system (CNS), where overcoming proactive brain barriers is crucial for the efficacy of genetic therapeutics. This research aimed to create ionizable nanoemulsions (iNEs), a new generation of RNA delivery systems with enhanced diffusivity. The developed iNEs (consisting of the combination of C12-200, DOPE, Vitamin E, and DMG-PEG) with a size below 100 nm, neutral surface charge, and high RNA loading capacity, showed excellent cell viability and transfection efficiency in various cellular models, including neurons, astrocytes, and microglia. Subsequently, iNEs containing mRNA GFP were tested for CNS transfection, highlighting their exceptional diffusivity and selective transfection of neurons following intra-parenchymal administration.

Keywords: Brain delivery; Diffusivity; Nanoemulsion; RNA therapeutics; mRNA; siRNA.

MeSH terms

  • Animals
  • Astrocytes / metabolism
  • Cell Survival / drug effects
  • Central Nervous System / metabolism
  • Diffusion
  • Emulsions*
  • Gene Transfer Techniques
  • Green Fluorescent Proteins / genetics
  • Humans
  • Lipids / chemistry
  • Microglia / metabolism
  • Nanoparticles* / chemistry
  • Neurons* / metabolism
  • Phosphatidylethanolamines
  • Polyethylene Glycols / chemistry
  • RNA* / administration & dosage
  • RNA, Messenger / administration & dosage
  • Transfection* / methods
  • Vitamin E / administration & dosage
  • Vitamin E / chemistry

Substances

  • Emulsions
  • RNA
  • Vitamin E
  • Polyethylene Glycols
  • Lipids
  • dioleoyl phosphatidylethanolamine
  • RNA, Messenger
  • Green Fluorescent Proteins
  • Phosphatidylethanolamines