Green synthesis of nanocellulose supported cu-bionanocomposites and their profound applicability in the synthesis of amide derivatives and controlling of food-borne pathogens

Abstract

Copper bionanocomposites (CBNCS) were synthesized using Ipomoea carnea- sourced nanocellulose as support via an eco-friendly and cost-effective method. X-ray Diffractometer (XRD) pattern of CBNCS confirmed the octahedral structure of Cu₂O, the face-centered cubic (FCC) crystal structure of Cu(0). XRD also revealed the crystal lattice of cellulose II. Surface Electron Microscope (SEM) and Transmission Electron Microscope (TEM) revealed the uniform distribution of copper nanoparticles (Cu NPs) with an average size of 10 nm due to the presence of nanocellulose. X-ray photoelectron spectroscopy (XPS) provided information about the electronic, chemical state and elemental composition of CBNCS. Thermogravimetric Analysis (TGA) showed the thermal stability of CBNCS. CBNCS catalyzed the rearrangement of oximes to primary amides in a very mild condition with a high yield of up to 92 %. CBNCS effectively inhibited the growth of Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli) with lower minimum inhibitory concentration MIC values. Antioxidant activity and electrical conductivity of CBNCS were also determined.

Keywords: Catalytic & biomedical activity; Cu-bionanocomposites; Nanocellulose; Rearrangement.