Flash entropy search to query all mass spectral libraries in real time

Nat Methods. 2023 Oct;20(10):1475-1478. doi: 10.1038/s41592-023-02012-9. Epub 2023 Sep 21.

Abstract

Public repositories of metabolomics mass spectra encompass more than 1 billion entries. With open search, dot product or entropy similarity, comparisons of a single tandem mass spectrometry spectrum take more than 8 h. Flash entropy search speeds up calculations more than 10,000 times to query 1 billion spectra in less than 2 s, without loss in accuracy. It benefits from using multiple threads and GPU calculations. This algorithm can fully exploit large spectral libraries with little memory overhead for any mass spectrometry laboratory.

MeSH terms

  • Algorithms*
  • Entropy*
  • Mass Spectrometry / methods
  • Metabolomics* / methods
  • Software*
  • Tandem Mass Spectrometry / methods