Synchrotron-based operando X-ray diffraction and X-ray absorption spectroscopy study of LiCo0.5Fe0.5PO4 mixed d-metal olivine cathode

Taymour A Hamdalla; Abdelaziz M Aboraia; V V Shapovalov; A A Guda; N V Kosova; O A Podgornova; A A A Darwish; S A Al-Ghamdi; S Alfadhli; Aadel M Alatawi; Alexander Soldatov

doi:10.1038/s41598-023-28951-z

Synchrotron-based operando X-ray diffraction and X-ray absorption spectroscopy study of LiCo_0.5Fe_0.5PO₄ mixed d-metal olivine cathode

Sci Rep. 2023 Feb 7;13(1):2169. doi: 10.1038/s41598-023-28951-z.

Authors

Taymour A Hamdalla^{1

2}, Abdelaziz M Aboraia³, V V Shapovalov⁴, A A Guda⁴, N V Kosova⁵, O A Podgornova⁵, A A A Darwish^{6

7}, S A Al-Ghamdi⁶, S Alfadhli⁶, Aadel M Alatawi⁸, Alexander Soldatov⁴

Affiliations

¹ Department of Physics, Faculty of Science, University of Tabuk, 71491, Tabuk, Saudi Arabia. t-ahmed@ut.edu.sa.
² Department of Physics, Faculty of Science, Alexandria University, Alexandria, Egypt. t-ahmed@ut.edu.sa.
³ Physics Department, Faculty of Science, Al-Azhar University, Assiut, 71542, Egypt. a.m.aboraia@gmail.com.
⁴ The Smart Materials Research Institute, Southern Federal University, Sladkova, Russia.
⁵ Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch of the Russian Academy of Sciences, 18 Kutateladze, 630128, Novosibirsk, Russia.
⁶ Department of Physics, Faculty of Science, University of Tabuk, 71491, Tabuk, Saudi Arabia.
⁷ Department of Physics, Sana'a University, Sana'a, Yemen.
⁸ Electrical Engineering Department, Faculty of Engineering, Tabuk University, Tabuk, Saudi Arabia.

Abstract

Lithium-ion batteries based on high-voltage cathode materials, such as LiCoPO₄, despite being promising in terms of specific power, still suffer from poor cycle life due to the lower stability of common non-aqueous electrolytes at higher voltages. One way to overcome this issue might be decreasing the working potential of the battery by doping LiCoPO₄ by Fe, thus reducing electrolyte degradation upon cycling. However, such modification requires a deep understanding of the structural behavior of cathode material upon lithiation/delithiation. Here we used a combination of operando synchrotron-based XRD and XAS to investigate the dynamics of d-metal local atomic structure and charge state upon cycling of LiCo_0.5Fe_0.5PO₄ mixed d-metal olivine cathode material. Principal components analysis (PCA) of XAS data allowed the extraction of spectra of individual phases in the material and their concentrations. For both Co and Fe two components were extracted, they correspond to fully lithiated and delithiated phases of Li_xMPO₄ (where M = Fe, Co). Thus, we were able to track the phase transitions in the material upon charge and discharge and quantitatively analyze the M²⁺/M³⁺ electrochemical conversion rate for both Fe and Co. Rietveld's refinement of XRD data allowed us to analyze the changes in the lattice of cathode material and their reversibility upon (de)lithiation during cycling. The calculation of DFT and Bader charge analysis expects the oxygen redox procedure combined with d-metals redox, which supplements iron charge variations and dominates at high voltages when x < 0.75 in Li_xCoFePO₄.

Grants and funding

0007-1442-S/Ministry of Education - Kingdom of Saudi Arabi