Synthesis of NaA zeolite from foundry dust and its adsorption capacity of ammonia

Abstract

Eutrophication of water bodies due to excess ammonia nitrogen (NH₄⁺-N) is harmful to aquatic organisms and human health. In this study, foundry dust (FD) from foundry industry was used to synthesize NaA zeolite to use as an adsorbent to remove NH₄⁺-N from wastewater. Results demonstrate that FD could be successfully synthesized to form a foundry dust-based NaA zeolite (FZA) through adjustment of the silica-alumina ratio of n (SiO₂)/n (Al₂O₃) at 2 at 95 °C. Specific surface area, total pore volume, and cation exchange capacity (CEC), and maximum adsorption NH₄⁺-N of FZA was respectively 43.185 cm²/g, 0.0364 cm³/g, 212.35 mmol/100 g and 37.81 mg/g, which was 4.74, 1.54, 1.52 and 1.62 times as much as the NaA zeolite (SZA). FZA with higher adsorption NH₄⁺-N capacity was related to higher specific surface area and CEC. The NH₄⁺-N adsorption amount of 28.57 mg/g by FZA was obtained after the fourth regeneration, which was notably higher than that of SZA (23.27 mg/g). The desorption rate of NH₄⁺-N from FZA was 87% by the fourth regeneration. FZA effectively removed NH₄⁺-N from swine wastewater containing 153.32 mg/L NH₄⁺-N. Results suggest that FZA could be used as absorbent to removal NH₄⁺-N from wastewater.

Keywords: Adsorption; Ammonia; Solid waste; Swine wastewater; Synthesis; Zeolite.