Discovery of Novel Pyrazole-Based KDM5B Inhibitor TK- 129 and Its Protective Effects on Myocardial Remodeling and Fibrosis

J Med Chem. 2022 Oct 13;65(19):12979-13000. doi: 10.1021/acs.jmedchem.2c00797. Epub 2022 Sep 16.

Abstract

Lysine-specific demethylase 5B (KDM5B) has been recognized as a potential drug target for cardiovascular diseases. In this work, we first found that the KDM5B level was increased in mouse hearts after transverse aortic constriction (TAC) and in Ang II-induced activated cardiac fibroblasts. Structure-based design and further optimizations led to the discovery of highly potent pyrazole-based KDM5B inhibitor TK-129 (IC50 = 0.044 μM). TK-129 reduced Ang II-induced activation of cardiac fibroblasts in vitro, exhibited good PK profile (F = 42.37%), and reduced isoprenaline-induced myocardial remodeling and fibrosis in vivo. Mechanistically, we found that KDM5B up-regulation in cardiac fibroblast activation was associated with the activation of Wnt-related pathway. The protective effects of TK-129 were associated with its KDM5B inhibition and blocking KDM5B-related Wnt pathway activation. Taken together, TK-129 may represent a novel KDM5-targeting lead compound for cardiac remodeling and fibrosis.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • DNA-Binding Proteins / metabolism
  • Fibrosis
  • Isoproterenol
  • Jumonji Domain-Containing Histone Demethylases / metabolism
  • Lysine* / metabolism
  • Mice
  • Myocardium* / metabolism
  • Pyrazoles / metabolism
  • Pyrazoles / pharmacology
  • Pyrazoles / therapeutic use

Substances

  • DNA-Binding Proteins
  • Pyrazoles
  • Jumonji Domain-Containing Histone Demethylases
  • Kdm5b protein, mouse
  • Lysine
  • Isoproterenol