Identification of potent small molecule inhibitors of SARS-CoV-2 entry

SLAS Discov. 2022 Jan;27(1):8-19. doi: 10.1016/j.slasd.2021.10.012. Epub 2021 Oct 23.

Abstract

The severe acute respiratory syndrome coronavirus 2 responsible for COVID-19 remains a persistent threat to mankind, especially for the immunocompromised and elderly for which the vaccine may have limited effectiveness. Entry of SARS-CoV-2 requires a high affinity interaction of the viral spike protein with the cellular receptor angiotensin-converting enzyme 2. Novel mutations on the spike protein correlate with the high transmissibility of new variants of SARS-CoV-2, highlighting the need for small molecule inhibitors of virus entry into target cells. We report the identification of such inhibitors through a robust high-throughput screen testing 15,000 small molecules from unique libraries. Several leads were validated in a suite of mechanistic assays, including whole cell SARS-CoV-2 infectivity assays. The main lead compound, calpeptin, was further characterized using SARS-CoV-1 and the novel SARS-CoV-2 variant entry assays, SARS-CoV-2 protease assays and molecular docking. This study reveals calpeptin as a potent and specific inhibitor of SARS-CoV-2 and some variants.

Keywords: Anti-viral drugs; HTS; Inhibitor; SARS-CoV-2; Virus entry.

MeSH terms

  • Angiotensin-Converting Enzyme 2 / metabolism
  • Animals
  • Antiviral Agents / pharmacology*
  • COVID-19 Drug Treatment*
  • Cathepsin L / antagonists & inhibitors
  • Cell Line
  • Chlorocebus aethiops
  • Cysteine Proteinase Inhibitors / pharmacology*
  • Dipeptides / pharmacology*
  • Drug Evaluation, Preclinical
  • Drug Repositioning
  • HEK293 Cells
  • Humans
  • Molecular Docking Simulation
  • SARS-CoV-2 / drug effects
  • SARS-CoV-2 / growth & development
  • Serine Endopeptidases / metabolism
  • Spike Glycoprotein, Coronavirus / metabolism
  • Vero Cells
  • Virus Attachment / drug effects*
  • Virus Internalization / drug effects*

Substances

  • Antiviral Agents
  • Cysteine Proteinase Inhibitors
  • Dipeptides
  • Spike Glycoprotein, Coronavirus
  • spike protein, SARS-CoV-2
  • calpeptin
  • ACE2 protein, human
  • Angiotensin-Converting Enzyme 2
  • Serine Endopeptidases
  • TMPRSS2 protein, human
  • CTSL protein, human
  • Cathepsin L

Supplementary concepts

  • SARS-CoV-2 variants