The synergistic effect of carbon edges and dopants towards efficient oxygen reduction reaction

Abstract

Decoration with alien atoms and increasing the edge content are two valid ways to activate the oxygen reduction reaction (ORR) property of nanocarbons. To further enhance their intrinsic activity and explore the underlying ORR mechanism, graphene nanoribbons (GNRs) were selected as an ideal catalyst model. Theoretical simulations have predicted that with the synergistic effect between heteroatom-doping and edge sites, the ORR activity can be significantly improved. Inspired by this, N-GNRs were synthesized via the oxidative unzipping of CNTs followed by nitrogen incorporation with urea. Ample edges and nitrogen doping sites were detected by high-resolution transmission electron microscopy and X-ray photoelectron spectroscopy, respectively. As a result, N-GNRs exhibited remarkably higher ORR properties in terms of onset and half-wave potentials, Tafel slopes, electron transfer number and methanol tolerance than either GNRs, the control sample without doping, or N-CNTs, the control sample without abundant edges, simply clarifying the significance of synergy between dopants and edges. Thus, this work provides a simple but efficient strategy to fabricate high-performance oxygen reduction catalysts.

Keywords: Density functional theory; Edge sites; Graphene nanoribbons; Heteroatom doping; Oxygen reduction reaction.