Ag@WS2 quantum dots for Surface Enhanced Raman Spectroscopy: Enhanced charge transfer induced highly sensitive detection of thiram from honey and beverages

Abstract

Novel SERS substrates is urgently in demand for rapid and sensitive analysis of toxic agrochemicals from food. In this work, a monodispersed tungsten disulfide quantum dots modified silver nanosphere (Ag@WS₂QD) was prepared and used as SERS substrate. Ag@WS₂QD generated uniform and stable SERS signals within 2 min, displaying great promise in "mixing and reading" detection. Compared to unmodified colloidal silver nanoparticles, 4 times higher analytical enhancement factor was found in Ag@WS₂QD. Density functional theory calculation verified the enhanced charge transfer within the coupling systems of molecule-Ag@WS₂QD. Besides, the unique surface properties are beneficial for the enrichment of specific molecule. Both the chemical extraction and enhanced charge transfer contributes to rapid and sensitive SERS detection of Ag@WS₂QD. A "mixing and reading" SERS method for thiram from honey and four kinds of juice was developed from Ag@WS₂QD, showing great promise for rapid and direct SERS detection for toxic agrochemicals and further applications.

Keywords: Charge transfer; Malachite Green (PubChem CID: 11294); Pesticide analysis; Quantum dots; Surface Enhanced Raman Spectroscopy; Thiram; Thiram (PubChem CID: 5455); Tungsten disulfide.