Usnic acid enantiomers restore cognitive deficits and neurochemical alterations induced by Aβ1-42 in mice

Behav Brain Res. 2021 Jan 15:397:112945. doi: 10.1016/j.bbr.2020.112945. Epub 2020 Oct 3.

Abstract

Alzheimer's disease (AD) is the most prevalent form of dementia with a complex pathophysiology not fully elucidated but with limited pharmacological treatment. The Usnic acid (UA) is a lichen secondary metabolite found in two enantiomeric forms: (R)-(+)-UA or (S)-(-)-UA, with antioxidant and anti-inflammatory potential. Thus, given the role of neuroinflammation and oxidative injury in the AD, this study aimed to investigate experimentally the cognitive enhancing and anti-neuroinflammatory effects of UA enantiomers. First, the interactions of UA on acetylcholinesterase (AChE) was assessed by molecular docking and its inhibitory capability on AChE was assessed in vitro. In vivo trials investigated the effects of UA enantiomers in mice exposed to Aβ1-42 peptide (400 pmol/mice) intracerebroventricularly (i.c.v.). For this, mice were treated orally during 24 days with (R)-(+)-UA or (S)-(-)-UA at 25, 50, or 100 mg/kg, vehicle, or donepezil (2 mg/kg). Animals were submitted to the novel object recognized, Morris water maze, and inhibitory-avoidance task to assess the cognitive deficits. Additionally, UA antioxidant capacity and neuroinflammatory biomarkers were measured at the cortex and hippocampus from mice. Our results indicated that UA enantiomers evoked complex-receptor interaction with AChE like galantamine in silico. Also, UA enantiomers improved the learning and memory of the animals and in parallel decreased the myeloperoxidase activity and the lipid hydroperoxides (LOOH) on the cortex and hippocampus and reduced the IL-1β levels on the hippocampus. In summary, UA restored the cognitive deficits, as well as the signs of LOOH and neuroinflammation induced by Aβ1-42 administration in mice.

Keywords: Alzheimer’s disease; Amyloid-β; Enantiomers; Memory; Neuroinflammation; Usnic acid.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Acetylcholinesterase / drug effects*
  • Alzheimer Disease / drug therapy*
  • Amyloid beta-Peptides / administration & dosage
  • Amyloid beta-Peptides / pharmacology*
  • Animals
  • Anti-Inflammatory Agents / administration & dosage
  • Anti-Inflammatory Agents / pharmacology*
  • Antioxidants / administration & dosage
  • Antioxidants / pharmacology*
  • Behavior, Animal / drug effects
  • Benzofurans / administration & dosage
  • Benzofurans / pharmacology*
  • Cerebral Cortex / drug effects*
  • Cerebral Cortex / immunology
  • Cognitive Dysfunction / chemically induced*
  • Cognitive Dysfunction / drug therapy*
  • Disease Models, Animal
  • Female
  • Hippocampus / drug effects
  • Hippocampus / immunology
  • Inflammation / chemically induced
  • Inflammation / drug therapy*
  • Injections, Intraventricular
  • Interleukin-1beta / drug effects
  • Mice
  • Molecular Docking Simulation
  • Nootropic Agents / administration & dosage
  • Nootropic Agents / pharmacology*
  • Peptide Fragments / administration & dosage
  • Peptide Fragments / pharmacology*

Substances

  • Amyloid beta-Peptides
  • Anti-Inflammatory Agents
  • Antioxidants
  • Benzofurans
  • IL1B protein, mouse
  • Interleukin-1beta
  • Nootropic Agents
  • Peptide Fragments
  • amyloid beta-protein (1-42)
  • usnic acid
  • Acetylcholinesterase