A stimuli-responsive combination therapy for recovering p53-inactivation associated drug resistance

Mater Sci Eng C Mater Biol Appl. 2020 Mar:108:110403. doi: 10.1016/j.msec.2019.110403. Epub 2019 Nov 6.

Abstract

Drug resistance is a major hindrance in the anticancer treatment, which encourages the development of effective therapeutic strategies. For the first time, MDM2-mediated p53 degradation was identified as a critical factor for developing acquired resistance of doxorubicin (DOX) in HepG2 tumor spheroids, which could be effectively reversed by MDM2 inhibitor MI-773, thereby improving anticancer effects. Therefore, a pH-sensitive liposomal formulation of DOX and MI-773 (LipD/M@CMCS) were developed for recovering p53-mediated DOX resistance in hepatocellular carcinoma. LipD/M@CMCS were composed of cationic liposomes covered with carboxymethyl chitosan (pI = 6.8), and were stable in the physiological condition (pH 7.4), but rapidly converted to cationic liposomes in tumor acidic microenvironment (pH 6.5), endowing them with tumor specificity and enhanced cellular uptake. We showed that LipD/M@CMCS could not only effectively induce cell apoptosis in HepG2 tumor spheroids, but significantly inhibit tumor growth with minimal adverse effects. In summary, selective regulation of MDM2 in cancer cells is a promising strategy to overcome DOX resistance, and may provide a perspective on the management of malignant tumors.

Keywords: Chemotherapy; Drug resistance; MDM2 inhibitor; Tumor spheroids; pH sensitive delivery systems.

MeSH terms

  • Animals
  • Antineoplastic Combined Chemotherapy Protocols / pharmacokinetics
  • Antineoplastic Combined Chemotherapy Protocols / pharmacology*
  • Antineoplastic Combined Chemotherapy Protocols / therapeutic use
  • Cell Cycle / drug effects
  • Doxorubicin / administration & dosage
  • Doxorubicin / pharmacokinetics
  • Doxorubicin / pharmacology
  • Drug Delivery Systems / methods*
  • Drug Liberation
  • Drug Resistance, Neoplasm / drug effects*
  • Hep G2 Cells
  • Humans
  • Hydrogen-Ion Concentration
  • Indoles / pharmacokinetics
  • Indoles / pharmacology*
  • Indoles / therapeutic use
  • Liposomes / administration & dosage
  • Liposomes / chemistry*
  • Mice, Nude
  • Proto-Oncogene Proteins c-mdm2 / antagonists & inhibitors
  • Pyrrolidines / pharmacokinetics
  • Pyrrolidines / pharmacology*
  • Pyrrolidines / therapeutic use
  • Spheroids, Cellular / drug effects
  • Spheroids, Cellular / pathology
  • Tissue Distribution
  • Tumor Microenvironment / drug effects
  • Tumor Suppressor Protein p53 / metabolism*
  • Xenograft Model Antitumor Assays

Substances

  • Indoles
  • Liposomes
  • MI-773
  • Pyrrolidines
  • TP53 protein, human
  • Tumor Suppressor Protein p53
  • Doxorubicin
  • MDM2 protein, human
  • Proto-Oncogene Proteins c-mdm2