Rational Design of a Bifunctional AND-Gate Ligand To Modulate Cell-Cell Interactions

ACS Synth Biol. 2020 Feb 21;9(2):191-197. doi: 10.1021/acssynbio.9b00273. Epub 2019 Dec 19.

Abstract

Protein "AND-gate" systems, in which a ligand acts only on cells with two different receptors, direct signaling activity to a particular cell type and avoid action on other cells. In a bifunctional AND-gate protein, the molecular geometry of the protein domains is crucial. Here we constructed a tissue-targeted erythropoietin (EPO) that stimulates red blood cell (RBC) production without triggering thrombosis. The EPO was directed to RBC precursors and mature RBCs by fusion to an anti-glycophorin A antibody V region. Many such constructs activated EPO receptors in vitro and stimulated RBC and not platelet production in mice but nonetheless enhanced thrombosis in mice and caused adhesion between RBCs and EPO-receptor-bearing cells. On the basis of a protein-structural model of the RBC surface, we rationally designed an anti-glycophorin-EPO fusion that does not induce cell adhesion in vitro or enhance thrombosis in vivo. Thus, mesoscale geometry can inform the design of synthetic-biological systems.

Keywords: erythropoietin; fusion protein; glycophorin A; nanobody; peptide linker; thrombosis.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Cell Communication / physiology*
  • Cell Line
  • Darbepoetin alfa / therapeutic use
  • Epitopes / genetics
  • Epitopes / metabolism
  • Erythrocytes / cytology
  • Erythrocytes / metabolism*
  • Erythropoietin / genetics
  • Erythropoietin / metabolism*
  • Glycophorins / immunology*
  • Glycophorins / metabolism
  • Hemorrhage / drug therapy
  • Humans
  • Ligands
  • Mice
  • Mice, Transgenic
  • Mutagenesis, Site-Directed
  • Protein Engineering
  • Recombinant Fusion Proteins / biosynthesis
  • Recombinant Fusion Proteins / isolation & purification
  • Recombinant Fusion Proteins / therapeutic use
  • Single-Chain Antibodies / genetics
  • Single-Chain Antibodies / metabolism

Substances

  • Epitopes
  • Glycophorins
  • Ligands
  • Recombinant Fusion Proteins
  • Single-Chain Antibodies
  • Erythropoietin
  • Darbepoetin alfa