Electrosprayed octenyl succinic anhydride starch capsules for rosemary essential oil encapsulation

Int J Biol Macromol. 2019 Jul 1:132:300-307. doi: 10.1016/j.ijbiomac.2019.03.203. Epub 2019 Mar 27.

Abstract

Octenyl succinic anhydride starch (OSA-starch) is often used as an emulsifier to protect bioactive compounds such as essential oils. In this study, rosemary essential oil was encapsulated in OSA-starch capsules via electrospraying an emulsion. Creaming was observed in the emulsions with 40% ethanol (v/v) 2 h after preparation, and phase separation occurred after 4 days. The emulsion with 20% ethanol revealed smaller droplets and lower zeta potential, and remained stable for 7 days. The morphology, loading capacity (LC), and encapsulation efficiency (EE) of the capsules, electrosprayed from the emulsions, were evaluated. The capsules from 20 and 30% aqueous ethanol (v/v) were smooth and spherical in shape with few dimpled. EE values were higher in the emulsions with 20% ethanol (82%-98%) when compared to those with 30% ethanol (89%-96%), except when 30% oil content was used. Fourier-transform infrared spectrometry suggested interaction of essential oil with the wall material. In summary, OSA-starch produced a stable emulsion that was suitable for electrospraying into capsules.

Keywords: Capsule; Electrospraying; Emulsion; Essential oil; OSA-starch.

MeSH terms

  • Capsules
  • Electricity*
  • Oils, Volatile / chemistry*
  • Starch / chemistry*
  • Succinic Anhydrides / chemistry*

Substances

  • Capsules
  • Oils, Volatile
  • Succinic Anhydrides
  • succinic anhydride
  • rosemary oil
  • Starch