Mammalian plasma fetuin-B is a selective inhibitor of ovastacin and meprin metalloproteinases

Sci Rep. 2019 Jan 24;9(1):546. doi: 10.1038/s41598-018-37024-5.

Abstract

Vertebrate fetuins are multi-domain plasma-proteins of the cystatin-superfamily. Human fetuin-A is also known as AHSG, α2-Heremans-Schmid-glycoprotein. Gene-knockout in mice identified fetuin-A as essential for calcified-matrix-metabolism and bone-mineralization. Fetuin-B deficient mice, on the other hand, are female infertile due to zona pellucida 'hardening' caused by the metalloproteinase ovastacin in unfertilized oocytes. In wildtype mice fetuin-B inhibits the activity of ovastacin thus maintaining oocytes fertilizable. Here we asked, if fetuins affect further proteases as might be expected from their evolutionary relation to single-domain-cystatins, known as proteinase-inhibitors. We show that fetuin-A is not an inhibitor of any tested protease. In stark contrast, the closely related fetuin-B selectively inhibits astacin-metalloproteinases such as meprins and ovastacin, but not astacins of the tolloid-subfamily, nor any other proteinase. The analysis of fetuin-B expressed in various mammalian cell types, insect cells, and truncated fish-fetuin expressed in bacteria, showed that the cystatin-like domains alone are necessary and sufficient for inhibition. This report highlights fetuin-B as a specific antagonist of ovastacin and meprin-metalloproteinases. Control of ovastacin was shown to be indispensable for female fertility. Meprin inhibition, on the other hand, renders fetuin-B a potential key-player in proteolytic networks controlling angiogenesis, immune-defense, extracellular-matrix-assembly and general cell-signaling, with implications for inflammation, fibrosis, neurodegenerative disorders and cancer.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Astacoidea
  • Cattle
  • Fertilization / physiology
  • Fetuin-B / metabolism*
  • Fibrinolysin / metabolism
  • Glycosylation
  • Humans
  • Mammals / blood*
  • Matrix Metalloproteinase 9 / metabolism
  • Metalloendopeptidases / metabolism*
  • Metalloproteases / antagonists & inhibitors
  • Metalloproteases / metabolism*
  • Mice
  • Plasma / metabolism*
  • Proteolysis
  • Recombinant Proteins / metabolism
  • alpha-2-HS-Glycoprotein / metabolism

Substances

  • Ahsg protein, mouse
  • Fetuin-B
  • Recombinant Proteins
  • alpha-2-HS-Glycoprotein
  • Astl protein, mouse
  • Metalloproteases
  • Fibrinolysin
  • Metalloendopeptidases
  • meprin A
  • ASTL protein, human
  • MMP9 protein, human
  • Matrix Metalloproteinase 9