Oxymatrine Causes Hepatotoxicity by Promoting the Phosphorylation of JNK and Induction of Endoplasmic Reticulum Stress Mediated by ROS in LO2 Cells

Mol Cells. 2018 May 31;41(5):401-412. doi: 10.14348/molcells.2018.2180. Epub 2018 May 10.

Abstract

Oxymatrine (OMT) often used in treatment for chronic hepatitis B virus infection in clinic. However, OMT-induced liver injury has been reported. In this study, we aim to investigate the possible mechanism of OMT-induced hepatotoxicity in human normal liver cells (L02). Exposed cells to OMT, the cell viability was decreased and apoptosis rate increased, the intracellular markers of oxidative stress were changed. Simultaneously, OMT altered apoptotic related proteins levels, including Bcl-2, Bax and pro-caspase-8/-9/-3. In addition, OMT enhanced the protein levels of endoplasmic reticulum (ER) stress makers (GRP78/Bip, CHOP, and cleaved-Caspase-4) and phosphorylation of c-Jun N-terminal kinase (p-JNK), as well as the mRNA levels of GRP78/Bip, CHOP, caspase-4, and ER stress sensors (IREI, ATF6, and PERK). Pre-treatment with Z-VAD-fmk, JNK inhibitor SP600125 and N-acetyl-l-cysteine (NAC), a ROS scavenger, partly improved the survival rates and restored OMT-induced cellular damage, and reduced caspase-3 cleavage. SP600125 or NAC reduced OMT-induced p-JNK and NAC significantly lowered caspase-4. Furthermore, 4-PBA, the ER stress inhibitor, weakened inhibitory effect of OMT on cells, on the contrary, TM worsen. 4-PBA also reduced the levels of p-JNK and cleaved-caspase-3 proteins. Therefore, OMT-induced injury in L02 cells was related to ROS mediated p-JNK and ER stress induction. Antioxidant, by inhibition of p-JNK or ER stress, may be a feasible method to alleviate OMT-induced liver injury.

Keywords: ER stress; JNK; L02 cell; apoptosis; hepatotoxicity; oxymatrine.

MeSH terms

  • Acetylcysteine / pharmacology
  • Alkaloids / pharmacology
  • Alkaloids / toxicity*
  • Amino Acid Chloromethyl Ketones / pharmacology
  • Anthracenes / pharmacology
  • Antioxidants / pharmacology
  • Antiviral Agents / pharmacology
  • Antiviral Agents / toxicity*
  • Apoptosis / drug effects
  • Butylamines / pharmacology
  • Cell Line
  • Chemical and Drug Induced Liver Injury / etiology
  • Endoplasmic Reticulum Chaperone BiP
  • Endoplasmic Reticulum Stress / drug effects*
  • Free Radical Scavengers / pharmacology
  • Gene Expression Regulation / drug effects
  • Hepatocytes / drug effects*
  • Hepatocytes / enzymology
  • Humans
  • JNK Mitogen-Activated Protein Kinases / metabolism*
  • Phosphorylation / drug effects
  • Protein Processing, Post-Translational / drug effects*
  • Quinolizines / pharmacology
  • Quinolizines / toxicity*
  • Reactive Oxygen Species / metabolism*

Substances

  • 4-phenylbutylamine
  • Alkaloids
  • Amino Acid Chloromethyl Ketones
  • Anthracenes
  • Antioxidants
  • Antiviral Agents
  • Butylamines
  • Endoplasmic Reticulum Chaperone BiP
  • Free Radical Scavengers
  • HSPA5 protein, human
  • Quinolizines
  • Reactive Oxygen Species
  • benzyloxycarbonylvalyl-alanyl-aspartyl fluoromethyl ketone
  • pyrazolanthrone
  • oxymatrine
  • JNK Mitogen-Activated Protein Kinases
  • Acetylcysteine