Imidazolium- and Triazine-Based Porous Organic Polymers for Heterogeneous Catalytic Conversion of CO2 into Cyclic Carbonates

Abstract

CO₂ adsorption and concomitant catalytic conversion into useful chemicals are promising approaches to alleviate the energy crisis and effects of global warming. This is highly desirable for developing new types of heterogeneous catalytic materials containing CO₂ -philic groups and catalytic active sites for CO₂ chemical transformation. Here, we present an imidazolium- and triazine-based porous organic polymer with counter chloride anion (IT-POP-1). The porosity and CO₂ affinity of IT-POP-1 may be modulated at the molecular level through a facile anion-exchange strategy. Compared with the post-modified polymers with iodide and hexafluorophosphate anions, IT-POP-1 possesses the highest surface area and the best CO₂ uptake capacity with excellent adsorption selectivity over N₂ . The roles of the task-specific components such as triazine, imidazolium, hydroxyl, and counter anions in CO₂ absorption and catalytic performance were illustrated. IT-POP-1 exhibits the highest catalytic activity and excellent recyclability in solvent- and additive-free cycloaddition reaction of CO₂ with epoxides.

Keywords: carbon dioxide; cyclic carbonates; imidazolium; porous organic polymers; triazine.