Synthesis of isoindolin-1-one derivatives via multicomponent reactions of methyl 2-formylbenzoate and intramolecular amidation

Mol Divers. 2016 Nov;20(4):859-865. doi: 10.1007/s11030-016-9679-6. Epub 2016 Jun 7.

Abstract

Four series of heterocyclic compounds were obtained using Ugi-type multicomponent reactions (MCRs) with methyl 2-formylbenzoate as one of the starting materials. A facile and efficient one-pot procedure was suitable for all the MCRs under acidic conditions. This process provided access to four series of complex and potentially biologically active scaffolds.

Keywords: Cyclization; Heterocycles; Intramolecular amidation; MCRs; One-pot procedure; UDC strategy; Ugi-type multicomponent reactions.

MeSH terms

  • Combinatorial Chemistry Techniques*
  • Cyclization
  • Heterocyclic Compounds / chemistry
  • Isoindoles / chemical synthesis*
  • Molecular Structure

Substances

  • Heterocyclic Compounds
  • Isoindoles