Efficient synthesis of highly substituted tetrahydroindazolone derivatives

Mol Divers. 2015 Aug;19(3):473-80. doi: 10.1007/s11030-015-9583-5. Epub 2015 Mar 18.

Abstract

A straightforward and efficient method for the synthesis of novel highly substituted and diversely functionalized indazolone derivatives has been developed. The transformation consists of a cyclocondensation of selected 1,3,3'-tricarbonyls with monosubstituted hydrazines. The starting β-triketones were prepared by an efficient chemo- and regioselective method under MW irradiation, exploiting the oxazolone chemistry. The reaction is easily accomplished under mild conditions and appears versatile, providing a synthetic diversification method with potential for drug-like compounds preparation.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Chemistry Techniques, Synthetic
  • Hydrazines / chemistry
  • Indazoles / chemical synthesis*
  • Indazoles / chemistry*

Substances

  • Hydrazines
  • Indazoles