Organocatalytic asymmetric conjugate addition of aldehydes to nitroolefins: identification of catalytic intermediates and the stereoselectivity-determining step by ESI-MS

Angew Chem Int Ed Engl. 2013 Nov 25;52(48):12619-23. doi: 10.1002/anie.201305338. Epub 2013 Oct 2.

Authors

Florian Bächle¹, Jörg Duschmalé, Christian Ebner, Andreas Pfaltz, Helma Wennemers

Affiliation

¹ University of Basel, Department of Chemistry, St. Johanns-Ring 19, 4056 Basel (Switzerland).

PMID: 24115304
DOI: 10.1002/anie.201305338

No abstract available

Keywords: asymmetric catalysis; mass spectrometry; organocatalysis; peptides; reaction mechanisms.