Difference in redox status of serum and aqueous humor in senile cataract patients as monitored via the albumin thiol-redox state

Jpn J Ophthalmol. 2010 Nov;54(6):584-8. doi: 10.1007/s10384-010-0877-y. Epub 2010 Dec 30.

Abstract

Purpose: To clarify the redox states of the aqueous humor and serum in senile cataract patients.

Methods: We analyzed the reduced and oxidized albumin fractions in 58 patients. The patients had no detectable evidence of other eye or systemic diseases and were divided into two age groups (53-75 and 76-96 years). Analysis was performed with a high-performance liquid chromatographic system with a fluorescence detector.

Results: Extremely small amounts of reduced albumin (3.8% and 3.6% in the younger and older groups, respectively) and markedly large amounts of oxidized albumin (96.2% and 96.4%, respectively) were found in the aqueous humor. Moreover, a higher percentage of oxidized albumin, particularly a highly oxidized irreversible form of albumin, was found in the aqueous humor (12.3% and 12.0%) than in the serum (2.4% and 3.0%).

Conclusions: In senile cataract patients with no complications, the redox state of albumin in the aqueous humor differs considerably, both quantitatively and qualitatively, from that in the serum.

MeSH terms

  • Aged
  • Aged, 80 and over
  • Aging / physiology
  • Aqueous Humor / metabolism*
  • Cataract / blood*
  • Cataract Extraction
  • Chromatography, High Pressure Liquid
  • Female
  • Humans
  • Male
  • Middle Aged
  • Oxidation-Reduction
  • Serum / metabolism
  • Serum Albumin / metabolism*
  • Serum Albumin, Human

Substances

  • Serum Albumin
  • mercaptoalbumin
  • nonmercaptalbumin
  • Serum Albumin, Human