A novel, selective, and efficacious nanomolar pyridopyrazinone inhibitor of V600EBRAF

Cancer Res. 2010 Oct 15;70(20):8036-44. doi: 10.1158/0008-5472.CAN-10-1366. Epub 2010 Aug 31.

Abstract

Oncogenic BRAF is a critical driver of proliferation and survival and is thus a validated therapeutic target in cancer. We have developed a potent inhibitor, termed 1t (CCT239065), of the mutant protein kinase, (V600E)BRAF. 1t inhibits signaling downstream of (V600E)BRAF in cancer cells, blocking DNA synthesis, and inhibiting proliferation. Importantly, we show that 1t is considerably more selective for mutated BRAF cancer cell lines compared with wild-type BRAF lines. The inhibitor is well tolerated in mice and exhibits excellent oral bioavailability (F = 71%). Suppression of (V600E)BRAF-mediated signaling in human tumor xenografts was observed following oral administration of a single dose of 1t. As expected, the growth rate in vivo of a wild-type BRAF human tumor xenograft model is unaffected by inhibitor 1t. In contrast, 1t elicits significant therapeutic responses in mutant BRAF-driven human melanoma xenografts.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Administration, Oral
  • Amino Acid Substitution
  • Animals
  • Breast Neoplasms / genetics
  • Breast Neoplasms / pathology
  • Cell Division
  • Cell Line, Tumor
  • Cell Survival
  • Colonic Neoplasms / genetics
  • Colonic Neoplasms / pathology
  • Enzyme Inhibitors / pharmacology
  • Enzyme-Linked Immunosorbent Assay
  • Extracellular Signal-Regulated MAP Kinases / metabolism
  • Female
  • Humans
  • Melanoma / genetics*
  • Melanoma / pathology
  • Mice
  • Mice, Inbred BALB C
  • Models, Molecular
  • Neoplasm Proteins / genetics*
  • Nucleic Acid Hybridization
  • Phosphorylation
  • Proto-Oncogene Proteins B-raf / genetics*
  • Transplantation, Heterologous

Substances

  • Enzyme Inhibitors
  • Neoplasm Proteins
  • BRAF protein, human
  • Proto-Oncogene Proteins B-raf
  • Extracellular Signal-Regulated MAP Kinases