Optimization and validation of a California halibut environmental estrogen bioassay using a heterologous ELISA

Sci Total Environ. 2009 Jan 1;407(2):953-61. doi: 10.1016/j.scitotenv.2008.09.046. Epub 2008 Nov 11.

Abstract

Vitellogenin, the estrogen-inducible yolk protein precursor, serves as an indicator of exposure to estrogen mimicking environmental contaminants. An ELISA for the measurement of California halibut plasma vitellogenin was optimized and validated using a commercially-available antibody developed for another flatfish species, turbot. Attempts to enhance assay performance by addition of a biotinylated antibody, polyethylene glycol, and Tween-20, and altering the preincubation step are described. Inclusion of overnight preincubation was critical for low detection limits. Increasing the amount of Tween-20 to 0.05% in buffers was most effective in achieving accurate quantification of spiked plasma samples. At the IC50, the average recovery of spiked plasma samples was 104% and the interplate CV was 12%. The working range of the assay was 33-1000 ng/mL, while the detection limit in a plasma sample is 2.2 microg/mL. The performance of this assay compared very well to a homologous assay demonstrating that commercially-available antibodies can facilitate the development of bioassays for local environmentally-relevant species. The dose response relationship of halibut Vg to the model compounds 17beta-estradiol and pnonylphenol show that it is a suitable model for further studies of estrogen mimicking contaminants.

Publication types

  • Research Support, Non-U.S. Gov't
  • Validation Study

MeSH terms

  • Animals
  • Antibodies, Monoclonal / immunology
  • Biological Assay / methods*
  • Biotin / chemistry
  • California
  • Dose-Response Relationship, Drug
  • Environmental Monitoring*
  • Enzyme-Linked Immunosorbent Assay / methods*
  • Estradiol / blood
  • Estradiol / toxicity
  • Estrogens / blood*
  • Estrogens / toxicity
  • Female
  • Flounder / blood*
  • Phenols / blood
  • Phenols / toxicity
  • Polyethylene Glycols / chemistry
  • Polysorbates / chemistry
  • Time Factors
  • Vitellogenins / blood
  • Vitellogenins / toxicity
  • Water Pollutants, Chemical* / blood
  • Water Pollutants, Chemical* / toxicity

Substances

  • Antibodies, Monoclonal
  • Estrogens
  • Phenols
  • Polysorbates
  • Vitellogenins
  • Water Pollutants, Chemical
  • Polyethylene Glycols
  • Estradiol
  • Biotin