Rhodium-catalyzed enantioselective desymmetrization of bicyclic hydrazines with alkynylboronic esters

Chem Commun (Camb). 2008 Jul 21:(27):3127-9. doi: 10.1039/b803693d. Epub 2008 May 8.

Abstract

The first successful asymmetric transfer of rhodium-alkynyl species to symmetrical strained alkenes has been realized starting from bicyclic hydrazines and alkynylboronic esters.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Boronic Acids / chemistry*
  • Bridged Bicyclo Compounds / chemistry*
  • Catalysis
  • Esters / chemistry*
  • Hydrazines / chemistry*
  • Rhodium / chemistry*
  • Stereoisomerism
  • Substrate Specificity

Substances

  • Boronic Acids
  • Bridged Bicyclo Compounds
  • Esters
  • Hydrazines
  • Rhodium