Model of full-length HIV-1 integrase complexed with viral DNA as template for anti-HIV drug design

J Comput Aided Mol Des. 2004 Dec;18(12):739-60. doi: 10.1007/s10822-005-0365-5. Epub 2005 Jun 27.

Abstract

We report structural models of the full-length integrase enzyme (IN) of the human immunodeficiency virus type 1 (HIV-1) and its complex with viral and human DNA. These were developed by means of molecular modeling techniques using all available experimental evidence, including X-ray crystallographic and NMR structures of portions of the full-length protein. Special emphasis was placed on obtaining a model of the enzyme's active site with the viral DNA apposed to it, based on the hypothesis that such a model would allow structure-based design of inhibitors that retain activity in vivo. This was because bound DNA might be present in vivo after 3'-processing but before strand transfer. These structural models were used to study the potential binding modes of various diketo-acid HIV-1 IN inhibitors (many of them preferentially inhibiting strand transfer) for which no experimentally derived complexed structures are available. The results indicate that the diketo-acid IN inhibitors probably chelate the metal ion in the catalytic site and also prevent the exposure of the 3'-processed end of the viral DNA to human DNA.

MeSH terms

  • Amino Acid Sequence
  • Anti-HIV Agents / chemistry*
  • Anti-HIV Agents / pharmacology
  • Base Sequence
  • Binding Sites
  • Computer Simulation
  • Crystallography, X-Ray
  • DNA / chemistry
  • DNA / genetics
  • DNA, Viral / chemistry
  • DNA, Viral / genetics
  • Drug Design
  • HIV Integrase / chemistry*
  • HIV Integrase / genetics
  • HIV-1 / drug effects
  • HIV-1 / enzymology*
  • HIV-1 / genetics
  • Humans
  • In Vitro Techniques
  • Macromolecular Substances
  • Models, Molecular
  • Molecular Sequence Data
  • Molecular Structure
  • Nuclear Magnetic Resonance, Biomolecular
  • Protein Structure, Tertiary
  • Static Electricity

Substances

  • Anti-HIV Agents
  • DNA, Viral
  • Macromolecular Substances
  • DNA
  • HIV Integrase