Coating noble metal nanocrystals (Ag, Au, Pd, and Pt) on polystyrene spheres via ultrasound irradiation

V G Pol; H Grisaru; A Gedanken

doi:10.1021/la047465d

Coating noble metal nanocrystals (Ag, Au, Pd, and Pt) on polystyrene spheres via ultrasound irradiation

Langmuir. 2005 Apr 12;21(8):3635-40. doi: 10.1021/la047465d.

Authors

V G Pol¹, H Grisaru, A Gedanken

Affiliation

¹ Department of Chemistry and Kanbar Laboratory for Nanomaterials at the Bar-Ilan University Center for Advanced Materials and Nanotechnology, Bar-Ilan University, Ramat-Gan 52900, Israel.

PMID: 15807613
DOI: 10.1021/la047465d

Abstract

The method of ultrasound irradiation is used for anchoring metallic nanocrystals (Ag, Au, Pd, and Pt) onto the surface of polystyrene spheres. In former studies, almost all the sonochemically prepared, coated metallic nanomaterials were formed as amorphous nanoparticles (Pol, V. G.; et al. Langmuir 2002, 18, 3352; Pol, V. G.; et al. Chem. Mater. 2003, 15, 1111; Zhong, Z. Y.; et al. Chem. Mater. 1999, 11 (9), 2350; Pol, V. G.; et al. Chem. Mater. 2003, 15, 1378), which were coated on various substrates (silica spheres, carbon spherules, titania, and alumina). On the other hand, the noble metal nanoparticles deposited on polystyrene spheres via ultrasound irradiation yielded nanocrystalline Ag, Au, Pd, and Pt particles on the surface of polystyrene as as-synthesized materials. The sonochemical mechanism is proposed based on chemical interactions between the particles.