A chiral layered Co(II) coordination polymer with helical chains from achiral materials

Ge Tian; Guangshan Zhu; Xiaoyu Yang; Qianrong Fang; Ming Xue; Jinyu Sun; Yan Wei; Shilun Qiu

doi:10.1039/b417184e

A chiral layered Co(II) coordination polymer with helical chains from achiral materials

Chem Commun (Camb). 2005 Mar 21:(11):1396-8. doi: 10.1039/b417184e. Epub 2005 Jan 26.

Authors

Ge Tian¹, Guangshan Zhu, Xiaoyu Yang, Qianrong Fang, Ming Xue, Jinyu Sun, Yan Wei, Shilun Qiu

Affiliation

¹ State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Department of Chemistry, Jilin University, Changchun, 130012, China.

PMID: 15756315
DOI: 10.1039/b417184e

Abstract

A layered coordination polymer Co(PDC)(H2O)2.H2O containing two helical chains was synthesized, and the resultant crystals were not racemic as evidenced by the observation of strong signals in vibrational circular dichroism (VCD) spectra.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Circular Dichroism
Cobalt / chemistry*
Crystallography, X-Ray
Models, Chemical
Molecular Structure
Polymers / chemical synthesis*
Polymers / chemistry*
Stereoisomerism

Substances

Polymers
Cobalt