Unexpected formation of a novel macrocyclic tetraphosphine: (RSSR)-1,9-dibenzyl-3,7,11,15-tetramesityl-1,9-diaza-3,7,11,15-tetraphosphacyclohexadecane

Roman N Naumov; Andrey A Karasik; Oleg G Sinyashin; Peter Lönnecke; Evamarie Hey-Hawkins

doi:10.1039/b313487c

Unexpected formation of a novel macrocyclic tetraphosphine: (RSSR)-1,9-dibenzyl-3,7,11,15-tetramesityl-1,9-diaza-3,7,11,15-tetraphosphacyclohexadecane

Dalton Trans. 2004 Feb 7:(3):357-8. doi: 10.1039/b313487c. Epub 2004 Jan 6.

Authors

Roman N Naumov¹, Andrey A Karasik, Oleg G Sinyashin, Peter Lönnecke, Evamarie Hey-Hawkins

Affiliation

¹ A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Kazan Scientific Center, Arbuzov str. 8, Kazan, Russian Federation, 420088.

PMID: 15252537
DOI: 10.1039/b313487c

Abstract

The title compound was synthesised in moderate yield via stereoselective self-assembly of two bisphosphine, four formaldehyde and two primary amine molecules.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Crystallography, X-Ray
Macrocyclic Compounds / chemical synthesis*
Models, Molecular
Molecular Structure
Phosphines / chemical synthesis*

Substances

(RSSR)-1,9-dibenzyl-3,7,11,15-tetramesityl-1,9-diaza-3,7,11,15-tetraphosphacyclohexadecane
Macrocyclic Compounds
Phosphines